This article presents a provably convergent battery estimation scheme based on a single particle model with electrolyte (SPMe) dynamics, by proposing a systematic methodology to estimate critical information such as electrode-level states, electrolyte dynamics, and cyclable lithium. Electrode-level state estimation suffers from weak observability originating from two standalone electrode dynamics, which is then aggravated by the addition of electrolyte dynamics. This lack of observability can be alleviated by exploiting lithium inventory conservation enabled by the Kalman decomposition, allowing one to separate out the unobservable subspace. Assuming the knowledge of cyclable lithium, a nonlinear state observer with provable convergence can be constructed for the SPMe model, using voltage and current measurements. To relax this strong assumption, a sensitivity-based parameter estimation scheme is also deployed to track cyclable lithium—a crucial physical variable for capacity fade. Ultimately, the estimation framework can perform finer monitoring and diagnosis of battery charge and health down to the level of individual electrode and the electrolyte. Experimental validation demonstrates < 1% estimation error for cyclable lithium inventory. Solid phase lithium concentration estimates, especially in the negative electrode, can be sensitive to disturbances in cyclable lithium.


    Access

    Check access

    Check availability in my library

    Order at Subito €


    Export, share and cite



    Title :

    Beyond Battery State of Charge Estimation: Observer for Electrode-Level State and Cyclable Lithium With Electrolyte Dynamics


    Contributors:


    Publication date :

    2023-12-01


    Size :

    2372580 byte




    Type of media :

    Article (Journal)


    Type of material :

    Electronic Resource


    Language :

    English



    Luenberger Observer for Lithium Battery State-of-Charge Estimation

    Barsali, Stefano / Ceraolo, Massimo / Li, Jiajing et al. | British Library Conference Proceedings | 2020


    La ville cyclable. Concept, conditions et impacts

    Héran, Frédéric | Online Contents | 1995


    State of charge estimation of a lithium-ion battery using robust non-linear observer approach

    Gholizadeh, Mehdi / Yazdizadeh, Alireza | IET | 2018

    Free access

    State of charge estimation of a lithium‐ion battery using robust non‐linear observer approach

    Gholizadeh, Mehdi / Yazdizadeh, Alireza | Wiley | 2019

    Free access

    La ville cyclable: concept, conditions et impacts

    Heran, F. / IG Velo beider Basel | British Library Conference Proceedings | 1995